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IB DP Physics 2025 HL Study Notes

2.1.2 Temperature Scales

Kelvin and Celsius Scales

Kelvin Scale

The Kelvin scale is a thermodynamic temperature scale where absolute zero, the theoretical temperature at which particles have minimum thermal motion, is zero Kelvin (0 K). This scale is a cornerstone in thermodynamics, and it’s imperative for students to familiarise themselves with its intricacies.

  • Absolute Zero: Absolute zero (0 K) is equivalent to -273.15°C. At this temperature, particles theoretically possess minimal motion, and no heat energy is emitted. It serves as the starting point of this absolute temperature scale.
  • Increment Value: Notably, a degree on the Kelvin scale is the same size as a degree on the Celsius scale. This consistent increment value is vital for scientific calculations and analyses, ensuring uniformity and precision.
Diagram showing Kelvin and Celcius Scales

Kelvin and Celcius Scales

Image Courtesy Socratic

Celsius Scale

On the other hand, the Celsius scale, commonly used in daily life and in many scientific arenas, is defined by two fixed points: the freezing and boiling points of water, marked at 0°C and 100°C respectively, at one standard atmosphere of pressure.

  • Freezing and Boiling Points: These reference points are critical for consistency in measurements and calculations globally. They anchor the scale, providing universally understood reference temperatures.
  • Relation to Kelvin: The interplay between Celsius and Kelvin is marked by a straightforward conversion, enhancing flexibility in diverse scientific and engineering contexts.

Temperature Conversion

The linear relationship between the Kelvin and Celsius scales facilitates straightforward conversions, a skill that is essential for any physics student to master.

Celsius to Kelvin

The process to convert Celsius to Kelvin is succinct, involving the addition of 273.15. Mathematically, this conversion is expressed as:

T(K) = T(°C) + 273.15

For instance, to convert 25°C to Kelvin:

T(K) = 25°C + 273.15 = 298.15 K

Kelvin to Celsius

Similarly, converting Kelvin to Celsius involves subtracting 273.15 from the Kelvin temperature. It is mathematically represented as:

T(°C) = T(K) - 273.15

Diagram explaining temperature conversion formulas

Temperature conversion formulas

Image Courtesy Cuemath

This conversion aids in making Kelvin temperatures more relatable, especially in contexts where Celsius is the norm.

Equivalence of Temperature Changes

The parity in temperature changes between the Kelvin and Celsius scales is a characteristic that underpins various scientific computations and analyses.

  • Incremental Change: This feature is instrumental in scientific studies involving temperature changes, simplifying processes and ensuring consistency across multiple platforms and studies.

Practical Implications

In practical and experimental setups, this equivalence ensures that shifting between these scales doesn’t require adjustments to the magnitude of the temperature change, simplifying calculations and analyses.

  • Experimental Consistency: This feature is fundamental in ensuring consistency in experimental outcomes, regardless of the chosen temperature scale.

Kinetic Energy and Temperature

The relationship between the kinetic energy of particles and temperature is particularly pronounced in gases. Here, the kinetic energy can be directly correlated to temperature, illuminating insights into the behaviour of particles at different energy states.

Mathematical Representation

The formula

Ek = 3/2 kBT

captures this relationship succinctly. Where,

  • Ek represents the average kinetic energy of particles,
  • kB denotes Boltzmann’s constant (1.380649 x 10-23 J/K),
  • T is the temperature in Kelvin.

Implications

This equation underscores several vital points:

  • Higher Temperature: An increase in temperature correlates to an increase in the average kinetic energy of particles. This dynamic is observable in the increased motion and energy transfers evident at higher temperatures.
  • Energy Distribution: The energy among particles is not uniform; hence, while the equation gives the average kinetic energy, individual particles may possess varied energy levels due to differences in speed and the occurrence of collisions.
Diagram showing a graphical representation of the change in the energy with increase and decrease in the temperature

Temperature and Energy

Image Courtesy CK12

Applications

Understanding this relationship is not just theoretical; it has profound practical implications:

  • Molecular Motion: It aids in comprehending molecular motion, predicting the behaviour of gases, and applying these insights in real-world situations.
  • Absolute Measurements: The Kelvin scale becomes particularly crucial in these scenarios, offering absolute measurements that are instrumental in theoretical and experimental physics.

In the depth of thermal physics, understanding the Kelvin and Celsius scales, their conversions, and the direct implications for particle kinetic energy is a foundational pillar. These insights not just weave through the academic fabric but have profound real-world applications, marking the beginning of a journey into the world of thermal energy transfers and the fascinating exploration of particle motion at different energy states. Every nuance, from the scale increments to the energy equations, paves the path for more advanced studies and applications in the world of physics.

FAQ

The Kelvin scale is preferred in scientific research because it's an absolute temperature scale. It begins at absolute zero, where particles theoretically have minimum motion and no thermal energy is emitted. This characteristic makes the Kelvin scale pivotal for calculations in thermodynamics and statistical mechanics, ensuring consistency and universality in scientific communication. Unlike the Celsius scale, which is based on the freezing and boiling points of water, the Kelvin scale provides a more fundamental and universal approach to measuring temperature, reducing ambiguities and inconsistencies that can arise from the relative nature of other temperature scales.

While the Kelvin scale is predominantly used in scientific contexts due to its absolute nature and direct relation to particle kinetic energy, it's not exclusively for scientific purposes. It can be used in any scenario where temperature measurement is required, including weather forecasting. However, the Celsius scale is often preferred in everyday contexts, including weather reporting, because it’s more intuitive for the general public, with easily identifiable reference points like the freezing and boiling points of water. The Kelvin scale, with its starting point at absolute zero, is less relatable for non-scientific everyday applications.

Absolute zero is theoretically the temperature at which particles have minimum thermal motion. Practically, it’s nearly impossible to reach due to the third law of thermodynamics, stating that the entropy of a perfect crystal approaches zero as the temperature approaches absolute zero. In the realm of quantum physics, reaching absolute zero would imply a system’s quantum ground state, where particles have the lowest allowed energy. This concept is foundational in quantum mechanics, underpinning phenomena like superconductivity and Bose-Einstein condensation, where particles behave in unusual, quantised ways that defy classical physics.

In principle, the average kinetic energy of particles increases with temperature. However, during phase changes, like melting or boiling, temperature can remain constant while energy is still absorbed or released by the substance. This energy facilitates the phase transition without increasing the kinetic energy of the particles. It's attributed to the potential energy changes as bonds between particles are broken or formed. Therefore, though generally temperature and kinetic energy are directly proportional, exceptions arise during phase changes where temperature remains constant amidst energy transfers.

The Kelvin scale doesn’t use the degree symbol because it’s an absolute scale, measuring the thermodynamic temperature. Each unit on the Kelvin scale is a Kelvin (K), not a degree Kelvin. This distinction underscores the fundamental difference between the Kelvin and Celsius scales. While the Celsius scale is a relative scale based on arbitrary points like the freezing and boiling points of water, the Kelvin scale begins at absolute zero, a fundamental limit of temperature. Dropping the degree symbol underscores the Kelvin scale's role in providing absolute, intrinsic temperature measurements, unanchored from specific material properties or phase transitions.

Practice Questions

A laboratory technician records the temperature of a substance to be 47°C. Convert this temperature to the Kelvin scale. Additionally, explain the relationship between the Kelvin and Celsius scales with reference to the increment value and absolute zero.

The temperature in Kelvin can be calculated using the formula T(K) = T(°C) + 273.15. Applying this, we get T(K) = 47°C + 273.15 = 320.15 K. The Kelvin and Celsius scales have a linear relationship, meaning a change in temperature of 1°C is equivalent to a change of 1 K. Absolute zero is 0 K, which translates to -273.15°C. At this point, all particles theoretically have minimal motion. So, although the scales have different starting points, they have identical increment values, making conversions straightforward and ensuring consistency in temperature change values across both scales.

Explain the relationship between the temperature of a gas in Kelvin and the average kinetic energy of its particles, providing an example with a gas at 300 K.

The temperature of a gas in Kelvin is directly proportional to the average kinetic energy of its particles. The formula Ek = 3/2 kBT encapsulates this relationship, where Ek is the average kinetic energy, kB is Boltzmann’s constant, and T is the temperature in Kelvin. For a gas at 300 K, the average kinetic energy of its particles would be higher than that of a gas at a lower temperature, demonstrating increased molecular motion. Each increment in temperature reflects a proportional increase in kinetic energy, illustrating the direct correlation between these two variables, fundamental in thermal physics.

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