Need help from an expert?
The world’s top online tutoring provider trusted by students, parents, and schools globally.
Alkenes are named based on the longest carbon chain containing the double bond, with the lowest possible number for the double bond.
In more detail, the rules for naming alkenes are as follows:
1. Identify the longest carbon chain that contains the double bond. This chain is the parent chain and its length determines the root name of the alkene (e.g., ethene, propene, butene, etc.).
2. Number the carbon atoms in the parent chain starting from the end closest to the double bond. The double bond should have the lowest possible number. For example, in propene, the double bond is between the first and second carbon atoms, so it is named as 1-propene.
3. If there are any substituents (groups attached to the parent chain), they should be indicated by their numerical position on the chain and their name should be prefixed to the name of the alkene. For example, if there is a methyl group on the second carbon of propene, it would be named as 2-methylpropene.
4. If there are multiple double bonds, the positions of all the double bonds should be indicated and the suffix should be changed to reflect the number of double bonds (e.g., diene, triene, etc.). For example, if there are two double bonds in a five-carbon chain, it would be named as 1,3-pentadiene.
5. If there are multiple substituents of the same type, use prefixes such as di-, tri-, tetra-, etc. to indicate the number of those substituents. For example, if there are two methyl groups on the second carbon of propene, it would be named as 2,2-dimethylpropene.
6. If there are different types of substituents, they should be listed in alphabetical order. For example, if there is a bromo group and a methyl group on the second carbon of propene, it would be named as 2-bromo-2-methylpropene.
Remember, the goal is to provide the most specific and clear name that accurately describes the structure of the alkene.
Study and Practice for Free
Trusted by 100,000+ Students Worldwide
Achieve Top Grades in your Exams with our Free Resources.
Practice Questions, Study Notes, and Past Exam Papers for all Subjects!
The world’s top online tutoring provider trusted by students, parents, and schools globally.