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The giant covalent structure significantly increases the melting points due to strong intermolecular forces that require high energy to break.
In a giant covalent structure, atoms are held together by strong covalent bonds in a lattice structure. This means that a large amount of energy is required to overcome these bonds and change the state of the substance from solid to liquid, resulting in high melting points.
Take for example, diamond and silicon dioxide, two substances with giant covalent structures. Diamond, the hardest known natural material, is made entirely of carbon atoms bonded to each other with strong covalent bonds. These bonds form a rigid tetrahedral structure, making diamond extremely hard and giving it a high melting point of approximately 3550 degrees Celsius.
Similarly, silicon dioxide, also known as silica or quartz, has a giant covalent structure. Each silicon atom is bonded to four oxygen atoms, and each oxygen atom is bonded to two silicon atoms. This forms a three-dimensional network of strong covalent bonds, which gives silicon dioxide a high melting point of approximately 1600 degrees Celsius.
In contrast, substances with simple molecular structures, such as iodine or ice, have much lower melting points. This is because they are held together by weak intermolecular forces, which require less energy to overcome.
In summary, the giant covalent structure significantly affects the melting points of substances. The strong covalent bonds in these structures require a large amount of energy to break, resulting in high melting points. This is why substances with giant covalent structures, such as diamond and silicon dioxide, have much higher melting points than substances with simple molecular structures.
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