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The term 'crystal lattice' in ionic compounds refers to the regular, repeating arrangement of ions in the compound.
In more detail, a crystal lattice is a three-dimensional structure composed of positive and negative ions arranged in a specific, repeating pattern. This structure is a fundamental characteristic of ionic compounds, which are formed when atoms transfer electrons to achieve a full outer shell of electrons, resulting in the formation of positively charged cations and negatively charged anions. These ions are then held together by strong electrostatic forces of attraction, known as ionic bonds.
The arrangement of ions in a crystal lattice is not random. Instead, it is determined by the relative sizes of the ions and the ratio of cations to anions in the compound. This results in a structure that maximises the attractions between oppositely charged ions and minimises the repulsions between like-charged ions. The resulting crystal lattice structure is highly ordered and symmetrical, which contributes to the unique properties of ionic compounds.
For example, ionic compounds typically have high melting and boiling points because a large amount of energy is required to overcome the strong ionic bonds and disrupt the crystal lattice. They are also generally hard and brittle, as any displacement of ions within the lattice can cause a build-up of repulsive forces that lead to the crystal shattering. Furthermore, when dissolved in water or melted, ionic compounds can conduct electricity as the ions are free to move and carry charge.
In summary, the term 'crystal lattice' in ionic compounds is significant as it describes the regular, repeating arrangement of ions that results from ionic bonding. This structure is responsible for many of the characteristic properties of ionic compounds, including their high melting and boiling points, hardness, brittleness, and ability to conduct electricity when in a liquid state or dissolved in water.
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