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Bond polarity refers to the distribution of electrical charge in a chemical bond between two atoms.
In a chemical bond, the atoms involved do not always share the electrons equally. This is because different atoms have different electronegativities, which is a measure of an atom's ability to attract shared electrons in a chemical bond. When two atoms with different electronegativities form a bond, the atom with the higher electronegativity will pull the shared electrons closer to itself. This results in a charge imbalance, with the more electronegative atom becoming slightly negative (δ-) and the less electronegative atom becoming slightly positive (δ+). This is what we refer to as bond polarity.
For example, consider a water molecule (H2O). Oxygen is more electronegative than hydrogen, so the shared electrons in the O-H bonds spend more time closer to the oxygen atom. This makes the oxygen end of the molecule slightly negative and the hydrogen end slightly positive, creating a polar bond.
However, not all bonds are polar. If two atoms have the same electronegativity, they will share the electrons equally and the bond will be nonpolar. For instance, in a molecule of nitrogen gas (N2), the two nitrogen atoms have the same electronegativity, so the bond between them is nonpolar.
Bond polarity is a crucial concept in chemistry because it influences several properties of molecules, including their shape, reactivity, and the types of forces they can participate in. For example, molecules with polar bonds often have higher boiling points than similar molecules with nonpolar bonds, because the polar molecules can form stronger intermolecular forces. Understanding bond polarity can also help you predict how a molecule will behave in a chemical reaction. For instance, in a reaction between a polar molecule and a nonpolar molecule, the polar molecule is likely to be the one that donates electrons, because its electrons are less tightly held.
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