Need help from an expert?
The world’s top online tutoring provider trusted by students, parents, and schools globally.
The Arrhenius equation and Eyring equation are used to calculate the rate of chemical reactions.
The Arrhenius equation is used to calculate the rate constant (k) of a chemical reaction at a certain temperature. It is given by k = Ae^(-Ea/RT), where A is the frequency factor, Ea is the activation energy, R is the gas constant and T is the temperature in Kelvin. This equation shows that the rate of a reaction increases with increasing temperature, as the exponential term becomes larger.
The Eyring equation is a modification of the Arrhenius equation that takes into account the effect of entropy on the rate of a reaction. It is given by k = (kBT/h) * e^(-ΔG‡/RT), where kB is the Boltzmann constant, h is Planck's constant, ΔG‡ is the activation energy in terms of free energy, and T is the temperature in Kelvin. This equation shows that the rate of a reaction depends not only on the activation energy, but also on the change in entropy that occurs during the reaction.
Both equations are important in understanding the factors that affect the rate of chemical reactions. They can be used to predict how changes in temperature, pressure, and other variables will affect the rate of a reaction, and to design experiments to test these predictions.
Study and Practice for Free
Trusted by 100,000+ Students Worldwide
Achieve Top Grades in your Exams with our Free Resources.
Practice Questions, Study Notes, and Past Exam Papers for all Subjects!
The world’s top online tutoring provider trusted by students, parents, and schools globally.