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Strong field ligands cause larger energy separations between d orbitals, while weak field ligands cause smaller separations.
In the ligand field theory, the strength of a ligand's interaction with a metal ion is determined by its ability to split the d orbitals of the metal ion. Strong field ligands, such as CN-, CO, and NH3, cause a large energy separation between the d orbitals, resulting in a low-spin complex. This means that the electrons will fill the lower energy orbitals before moving to the higher energy orbitals, resulting in a smaller magnetic moment.
On the other hand, weak field ligands, such as H2O and F-, cause a smaller energy separation between the d orbitals, resulting in a high-spin complex. This means that the electrons will fill the higher energy orbitals before moving to the lower energy orbitals, resulting in a larger magnetic moment.
The strength of the ligand also affects the colour of the complex. Strong field ligands typically form complexes that are colourless or have a low intensity colour, while weak field ligands form complexes that have a more intense colour.
Overall, the strength of the ligand determines the energy separation between the d orbitals, which in turn affects the spin state and magnetic moment of the complex, as well as its colour.
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